Carboalumination/Ni-catalyzed couplings. A short synthesis of verticipyrone
Author/Authors :
Lipshutz، نويسنده , , Bruce H. and Amorelli، نويسنده , , Benjamin، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Pages :
3
From page :
2144
To page :
2146
Abstract :
Verticipyrone (1) has been synthesized in six overall steps from commercially available ethyl-2-methylacetoacetate. This represents the first successful application of a modified Negishi carboalumination-nickel-catalyzed cross-coupling reaction to a chloromethylated pyrone.
