Author/Authors :
Fadeyi، نويسنده , , Olugbeminiyi O. and Nathan Daniels، نويسنده , , R. and DeGuire، نويسنده , , Sean M. and Lindsley، نويسنده , , Craig W.، نويسنده ,
Abstract :
The first total synthesis of polemannones B and C, higly oxygenated benzoxanthenones derivatives from Polemannia montana, is reported employing our new catalytic Cu(II)/sparteine system for β,β-phenolic couplings and tandem inverse-electron demand Diels–Alder reaction cascade in 75–90% yield.