Title of article
A synthetic study on gymnastatins F and Q: the tandem Michael and aldol reaction approach
Author/Authors
Murayama، نويسنده , , Kyoko and Tanabe، نويسنده , , Takamasa and Ishikawa، نويسنده , , Yuichi and Nakamura، نويسنده , , Kensuke and Nishiyama، نويسنده , , Shigeru، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
3191
To page
3194
Abstract
Gymnastatins F (1) and Q (2) were successfully synthesized using the tandem Michael and aldol reaction of the corresponding spirodienones with hemiacetal functions. Inspection of the optical purities of the substrates suggested that undesired racemization does not proceed during the tandem reaction. Results of theoretical calculations agreed with the ratio of the reaction outcome.
Keywords
Marine natural product , Gymnascella dankaliensis , Gymnastatin
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1864222
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