Title of article :
A dramatic effect of double bond configuration in N-oxy-3-aza Cope rearrangements—a simple synthesis of functionalised allenes
Author/Authors :
Pinto، نويسنده , , Luis F.V. and Glَria، نويسنده , , Paulo M.C. and Gomes، نويسنده , , Mلrio J.S. and Rzepa، نويسنده , , Henry S. and Prabhakar، نويسنده , , Sundaresan and Lobo، نويسنده , , Ana M.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Abstract :
The first examples of low temperature N-oxy-3-aza Cope rearrangements, leading to functionalised allenes are described, where the Z-configuration of the enaminic double bond in the rearranging system proves critical.
Keywords :
3-Aza Cope rearrangements , hydroxylamines , enamines , Allenes , Intermediates , transition states , configuration
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
