Author/Authors :
Millet، نويسنده , , Renaud and Bernardez، نويسنده , , Tania and Palais، نويسنده , , Laëtitia and Alexakis، نويسنده , , Alexandre، نويسنده ,
Abstract :
The desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand is described. The corresponding homoallylic alcohols are obtained in high yield, diastereoselectivity, and enantiomeric excess. Furthermore the first anti enantioselective desymmetrization with aromatic nucleophiles is reported.
