Title of article :
Pt–rGO–TiO2 nanocomposite by UV-photoreduction method as promising electrocatalyst for methanol oxidation
Author/Authors :
Qu، نويسنده , , Yunteng and Gao، نويسنده , , Yunzhi and Kong، نويسنده , , Fandong and Zhang، نويسنده , , Sheng and Du، نويسنده , , Lei and Yin، نويسنده , , Geping، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Pages :
8
From page :
12310
To page :
12317
Abstract :
Pt/TiO2-decorated reduced graphene oxide composite as catalyst for methanol electro-oxidation with three phase junction structure has been synthesized by UV-photoreduction (denoted as p-Pt/rGO@TiO2). The obtained p-Pt/rGO@TiO2 has been detailedly characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV) and chronoamperometry (CA). XRD and TEM characterizations indicate that photoreduction is favorable to anchoring Pt nanoparticles (NPs) (ca. 2.2 nm) at the interface between TiO2 and reduced graphene oxide (rGO), and forming the Pt, TiO2 and rGO three phase junction structure. P-Pt/rGO@TiO2 exhibits a higher activity for methanol electro-oxidation than m-Pt/rGO and m-Pt/rGO@TiO2 (prepared by microwave-assisted polyol process). Lifetime tests demonstrate that the electrochemical durability of p-Pt/rGO@TiO2 is improved by a factor of 2 or more as compared with m-Pt/rGO and m-Pt/rGO@TiO2. XPS characterizations of p-Pt/rGO@TiO2 reveal stronger interaction between Pt and support hybrid compared with m-Pt/rGO@TiO2, which facilitates poisoning species removal and prevents Pt nanoparticles from migrating/agglomerating on or detaching from carbon support. This provides a facile and promising strategy to improve both the activity and durability of electrocatalysts for DMFCs.
Keywords :
graphene , methanol oxidation , Three phase junction structure , Photoreduction
Journal title :
International Journal of Hydrogen Energy
Serial Year :
2013
Journal title :
International Journal of Hydrogen Energy
Record number :
1864831
Link To Document :
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