Title of article :
A RhCl(PPh3)3/BF3·OEt2 co-promoted direct C–C cross-coupling of alcohols at β-position with aldehydes
Author/Authors :
Zhang، نويسنده , , Shu-Yu and Tu، نويسنده , , Yong-Qiang and Fan، نويسنده , , Chun-An and Yang، نويسنده , , Ming and Zhang، نويسنده , , Fu-Min، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Abstract :
A novel RhCl(PPh3)3/BF3·OEt2 co-promoted direct C–C cross-coupling of primary and secondary alcohols at β-position with aldehyde was developed. This reaction could provide an efficient synthesis of a series of α,β-unsaturated aldehydes and diarylidene ketones, just from simple and easily available alcohols and aldehydes.
Keywords :
C–C coupling , C–H functionalization , Rhodium(I) catalyst , ? , ?-unsaturated carbonyl compound
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
