• Title of article

    A RhCl(PPh3)3/BF3·OEt2 co-promoted direct C–C cross-coupling of alcohols at β-position with aldehydes

  • Author/Authors

    Zhang، نويسنده , , Shu-Yu and Tu، نويسنده , , Yong-Qiang and Fan، نويسنده , , Chun-An and Yang، نويسنده , , Ming and Zhang، نويسنده , , Fu-Min، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2009
  • Pages
    4
  • From page
    4178
  • To page
    4181
  • Abstract
    A novel RhCl(PPh3)3/BF3·OEt2 co-promoted direct C–C cross-coupling of primary and secondary alcohols at β-position with aldehyde was developed. This reaction could provide an efficient synthesis of a series of α,β-unsaturated aldehydes and diarylidene ketones, just from simple and easily available alcohols and aldehydes.
  • Keywords
    C–C coupling , C–H functionalization , Rhodium(I) catalyst , ? , ?-unsaturated carbonyl compound
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2009
  • Journal title
    Tetrahedron Letters
  • Record number

    1864970