Author/Authors :
Severa، نويسنده , , Luk?? and V?vra، نويسنده , , Jan and Kohoutov?، نويسنده , , Anna and ???kov?، نويسنده , , Martina and ??lov?، نويسنده , , Tereza and H?vl، نويسنده , , Jakub and ?aman، نويسنده , , David and Pohl، نويسنده , , Radek and Adriaenssens، نويسنده , , Louis and Tepl?، نويسنده , , Filip، نويسنده ,
Abstract :
Ruthenium-catalyzed substitutions of carbon pronucleophiles, various [2+2+2] cycloadditions, and addition of a diazo compound to an alkyne are shown to proceed in the presence of air. Notably diverse catalytic manifolds remain supported under conditions generally regarded as prohibitive. Building on rare reports from the literature we show that a range of organometallic transformations based on reaction intermediates derived from (C5Me5)Ru or (C5H5)Ru moieties are air-compatible.
