Title of article
Alternative synthetic path to (−)-adalinine via a SmI2-promoted fragmentation of a 3-oxopyrrolidine derivative
Author/Authors
Honda، نويسنده , , Toshio and Hisa، نويسنده , , Chihiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
4654
To page
4657
Abstract
A novel and stereocontrolled synthetic path to a coccinellid alkaloid, (−)-adalinine, was established by employing the reductive carbon–nitrogen bond cleavage reaction and subsequent recyclization of a 3-oxopyrrolidine derivative with samarium diiodide, as key steps, where water was found to be the best proton source.
Keywords
Adalinine , Coccinellid alkaloid , fragmentation , Samarium diiodide , C–N bond cleavage
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865327
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