Title of article
Hexachloroethane: a highly efficient reagent for the synthesis of chlorosilanes from hydrosilanes
Author/Authors
Pongkittiphan، نويسنده , , Veerachai and Theodorakis، نويسنده , , Emmanuel A. and Chavasiri، نويسنده , , Warinthorn، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
5080
To page
5082
Abstract
A new and efficient chlorination protocol is presented for the preparation of chlorosilanes from hydrosilanes. A variety of chlorinating agents in combination with palladium(II) chloride as the catalyst are examined. Among them, hexachloroethane is found to be the best choice, furnishing the desired product in good to quantitative yields under mild conditions. Various hydrosilanes are used as starting materials to explore the scope of this reaction.
Keywords
Chlorinating agents , Chlorosilanes , palladium(II) chloride , Hexachloroethane , Hydrosilanes
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865630
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