Title of article
Determination of absolute configuration of C14−C23 fragment in symbiodinolide
Author/Authors
Han، نويسنده , , Chunguang and Yamano، نويسنده , , Yoshi and Kita، نويسنده , , Masaki and Takamura، نويسنده , , Hiroyoshi and Uemura، نويسنده , , Daisuke، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
5280
To page
5282
Abstract
The degradation product C14−C23 2 was obtained using ethenolysis with the 2nd-generation Hoveyda-Grubbs catalyst from 62-membered lactone in symbiodinolide (1). The absolute configurations of three chiral centers in fragment 2 were assigned as 17R, 18R, and 21R by a combination of J-based configuration analysis and the Mosher–Riguera method.
Keywords
Ethenolysis , 2nd-generation Hoveyda-Grubbs catalyst , absolute configuration , J-based configuration analysis
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865774
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