Title of article :
A new, enantioselective synthesis of (+)-isolaurepan
Author/Authors :
Pazos، نويسنده , , Gonzalo and Pérez-Jiménez، نويسنده , , Manuel and Gلndara، نويسنده , , Zoila and Gَmez، نويسنده , , Generosa and Fall، نويسنده , , Yagamare، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Abstract :
A highly enantioselective synthesis of 2,6-syn-disubstituted tetrahydropyrans from commercially available tri-O-acetyl-d-glucal, based on a thermal Claisen rearrangement, allows enantioselective synthesis of (+)-isolaurepan when combined with a ring expansion reaction using trimethylsilyldiazomethane.
Keywords :
Marine toxins , Claisen rearrangement , 26-syn-Disubstituted tetrahydropyrans , enantioselective synthesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
