Author/Authors :
Yang، نويسنده , , Baiyuan and Lin، نويسنده , , Weimin and Krchnak، نويسنده , , Viktor and Miller، نويسنده , , Marvin J.، نويسنده ,
Abstract :
Retro iminonitroso Diels–Alder reactions were investigated in both solution and solid phase. In thermal or Cu(I)-mediated reactions, interconversion of various nitroso cycloadducts occurred in the presence of separate dienes. Up to 99% of conversion was observed. Use of chiral ligands in the Cu(I)-mediated reactions gave new cycloadducts enantioselectively.
