Title of article
Di(ethylene glycol) vinyl ether: a highly efficient deactivating reagent for olefin metathesis catalysts
Author/Authors
Liu، نويسنده , , Weidong and Nichols، نويسنده , , Paul J. and Smith، نويسنده , , Nathan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
6103
To page
6105
Abstract
A highly efficient method for deactivating commonly used olefin metathesis catalysts is described. Inexpensive and commercially available di(ethylene glycol) vinyl ether is found to quench both first- and second-generation Grubbs’ carbenes in less than 10 min at room temperature. The resulting ruthenium byproducts are readily removed by silica gel purification.
Keywords
metathesis , RCM , Scavenger , Fisher carbene , Ruthenium
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866358
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