Author/Authors :
Hosokawa، نويسنده , , Seijiro and Mukaeda، نويسنده , , Yuki and Kawahara، نويسنده , , Ryo and Tatsuta، نويسنده , , Kuniaki، نويسنده ,
Abstract :
The first total synthesis and structural determination of benzopyrenomycin has been achieved. This synthesis contains remarkable transformations including cyclization to afford the benzanthrone skeleton, syn-selective vinylogous Mukaiyama aldol reaction, and radical cyclization with the benzanthrone attaching the iodoalkane chain.