Title of article
Acyclic ketene aminal phosphates derived from N,N-diprotected acetamides: stability and cross-couplings
Author/Authors
Simas، نويسنده , , Alessandro B.C. and de Sales، نويسنده , , Daniel L. and Pais، نويسنده , , Karla C.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
6977
To page
6980
Abstract
The synthesis of a stable ketene aminal phosphate (α-phosphoryloxy enecarbamate) derived from N,N-diprotected acetamide, bearing two different removable protecting groups, is disclosed. This synthetic intermediate underwent successful palladium-catalyzed cross-coupling reactions to afford functionalized enynes and dienes.
Keywords
Stille reaction , Suzuki reaction , Catalysis , Diene , Enyne
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866992
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