Title of article :
Hydrogen production from low temperature WGS reaction on co-precipitated Cu–CeO2 catalysts: An optimization of Cu loading
Author/Authors :
Jeong، نويسنده , , Dae-Woon and Na، نويسنده , , Hyun-Suk and Shim، نويسنده , , Jae-Oh and Jang، نويسنده , , Won-Jun and Roh، نويسنده , , Hyun-Seog and Jung، نويسنده , , Un Ho and Yoon، نويسنده , , Wang Lai، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
Low temperature water–gas shift (WGS) reaction has been carried out at the gas hourly space velocity of 72,152 h−1 over Cu–CeO2 catalyst prepared by a co-precipitation method. Cu loading was optimized to obtain highly active co-precipitated Cu–CeO2 catalysts for low temperature WGS. 80 wt% Cu–CeO2 exhibited the highest CO conversion as well as the most stable activity (XCO > 46% at 240 °C for 100 h). The excellent catalytic performance is mainly due to a strong metal to support interaction, resulting in the prevention of Cu sintering.
Keywords :
Water–gas shift reaction , Co-precipitated , Cu–CeO2 , Sintering , Strong metal to support interaction
Journal title :
International Journal of Hydrogen Energy
Journal title :
International Journal of Hydrogen Energy