Title of article
The reductive etherification of carbonyl compounds using polymethylhydrosiloxane activated by molecular iodine
Author/Authors
Yadav، نويسنده , , J.S and Subba Reddy، نويسنده , , B.V. and Shiva Shankar، نويسنده , , K. V. Swamy، نويسنده , , T.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
46
To page
48
Abstract
Aldehydes and ketones undergo a smooth reductive etherification by polymethylhydrosiloxane (PMHS) in the presence of a catalytic amount of molecular iodine under mild conditions to afford the corresponding symmetrical ethers in excellent yields. This new reagent system (PMHS/I2) provides a simple and convenient route for the preparation of symmetrical ethers from carbonyl compounds.
Keywords
molecular iodine , reductive etherification , polymethylhydrosiloxane , ethers , carbonyl compounds
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1870446
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