Title of article
Highly diastereoselective allylation reactions of dilithiated 4-(phenylsulfonyl)-cyclopent-2-enol
Author/Authors
Craig، نويسنده , , Donald and Lu، نويسنده , , Pengfei and White، نويسنده , , Andrew J.P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
99
To page
101
Abstract
A two-step synthesis of 4-(phenylsulfonyl)cyclopent-2-enol using epoxide ring-opening and ring-closing alkene metathesis is described. Treatment of the dianion of 4-(phenylsulfonyl)cyclopent-2-enol with allylic bromides gave the corresponding alkylated products with excellent to complete diastereoselectivity.
Keywords
coordination , Cyclopentene , Diastereoselective alkylation , Diene , ring-closing metathesis
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1870488
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