Author/Authors :
Okamoto، نويسنده , , Sentaro and He، نويسنده , , Jing-Qian and Ohno، نويسنده , , Chihaya and Oh-iwa، نويسنده , , Yuhji and Kawaguchi، نويسنده , , Yuhki، نويسنده ,
Abstract :
Ti(O-i-Pr)4/Me3SiCl/Mg reagent mediated McMurry coupling of aryl aldehydes to biaryl olefins at near room temperature. This low valent titanium (LVT) reagent also mediated the coupling of aldimines to 1,2-diamines (imino pinacol coupling).