Title of article :
Mg-promoted C-trifluoroacetylation of benzophenone
Author/Authors :
Maekawa، نويسنده , , Hirofumi and Ozaki، نويسنده , , Taro and Nishiguchi، نويسنده , , Ikuzo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
Mg-promoted reduction of benzophenones in the presence of ethyl trifluoroacetate and trimethylchlorosilane in N-methyl-2-pyrrolidinone afforded the corresponding cross-coupling products, which were easily transformed into C-trifluoroacetylated compounds of benzophenones through desilylation by tetrabutylammonium fluoride.
Keywords :
Trifluoroacetylation , cross-coupling , Electron transfer , Magnesium , Reduction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
