Title of article
Hydroperoxides and aryl diazonium salts as reagents for the functionalization of non-activated olefins
Author/Authors
Blank، نويسنده , , Olga and Raschke، نويسنده , , Nicole and Heinrich، نويسنده , , Markus R.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
1758
To page
1760
Abstract
Hydroperoxides, olefins, and arenediazonium salts selectively combine to give azo compounds via an iron(II)-mediated three-component reaction. Starting with a fragmentation liberating acetic acid, the hydroperoxides act as radical source and the diazonium ions as nitrogen-centered radical scavengers.
Keywords
radical reactions , Hydroperoxides , Olefin functionalization , Arenediazonium salts
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1871619
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