Title of article
Highly efficient and regioselective allylic amination of allylic alcohols catalyzed by [Mo3PdS4] cluster
Author/Authors
Tao، نويسنده , , Yinsong and Zhou، نويسنده , , Yuhan and Qu، نويسنده , , Jingping and Hidai، نويسنده , , Masanobu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
1982
To page
1984
Abstract
A highly efficient and regioselective allylation reaction of amines with allylic alcohols under mild conditions catalyzed by the cubane-type sulfido cluster [(Cp∗Mo)3S4Pd(dba)][PF6] with H3BO3 as an additive has been developed. A variety of amines and allylic alcohols are investigated, and in the case of allylic alcohols bearing substituents at either α- or γ-position only linear allylic amination products are obtained.
Keywords
Allylic alcohol , allylation , Cubane-type sulfido cluster , Boric acid
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1871881
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