Title of article :
Synthesis of azidochloromethane and azidobromomethane
Author/Authors :
Banert، نويسنده , , Klaus and Joo، نويسنده , , Young-Hyuk and Rüffer، نويسنده , , Tobias and Walfort، نويسنده , , Bernhard and Lang، نويسنده , , Heinrich، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
By treatment of tris(azidomethyl)amine with dry hydrogen halide, azidochloromethane and azidobromomethane were prepared. The former product, which is more stable than the latter, was isolated as a colorless liquid. The desired azidohalomethanes are intermediates in the nucleophilic substitution of dihalomethanes to generate diazidomethane but could not be detected in this transformation.
Keywords :
Azides , Hazardous compounds , nucleophilic substitution , Triazoles
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
