Author/Authors :
Deobald، نويسنده , , Anna Maria and Simon de Camargo، نويسنده , , Leandro R. and Tabarelli، نويسنده , , Greice and Hِrner، نويسنده , , Manfredo and Rodrigues، نويسنده , , Oscar E.D. and Alves، نويسنده , , Diego and Braga، نويسنده , , Antônio L.، نويسنده ,
Abstract :
We present here our results of the efficient synthesis of azido arylselenides and azido aryldiselenides under mild conditions. Starting from nitrogen-substituted benzenes, we incorporated selenium atom at aromatic ring and obtained amino arylselenides and diselenides in satisfactory yields. Treatment of these compounds with iso-pentyl nitrite (i-C5H11ONO) and azido trimethylsilane (Me3SiN3) in THF affords a variety of azido arylselenides and diselenides in good to excellent yields.
