Title of article
A new method for the stereoselective construction of angular methyl group of fuzed cyclic ethers
Author/Authors
Kadota، نويسنده , , Isao and Kishi، نويسنده , , Takayuki and Fujisawa، نويسنده , , Yuka and Yamagami، نويسنده , , Yuji and Takamura، نويسنده , , Hiroyoshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
2
From page
3960
To page
3961
Abstract
A convenient method for the stereoselective construction of angular methyl group of fuzed cyclic ethers is described. Reactions of mixed thioacetals with Me2Zn/Zn(OTf)2 afforded the corresponding methylated products in good yields. Various protective groups such as MOM ether, benzylidene acetal, TBS ether, and pivaloyl group were stable under the reaction conditions.
Keywords
Marine polycyclic ethers , Fuzed cyclic ethers , Angular methyl group , Mixed thioacetals
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1873730
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