Title of article :
Unexpected reactivity of 2-fluoro-4-(trifluoromethyl)-phenylacetonitrile: isolation and characterization of a trimeric impurity
Author/Authors :
Stazi، نويسنده , , Federica and Provera، نويسنده , , Stefano and Curcuruto، نويسنده , , Ornella and Westerduin، نويسنده , , Pieter and Bacchi، نويسنده , , Sergio، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
An uncommon reactivity of 2-fluoro-4-(trifluoromethyl)-phenylacetonitrile, with the loss of three fluorine atoms, is herein reported, the resulting trimeric compound was isolated and characterized by NMR and MS/MS studies. An unprecedented mechanism has been proposed.
Keywords :
Arylacetonitriles , Trifluoromethyl group , Fluorine anion , NMR , MS/MS
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
