Title of article :
Total synthesis of cryptopyranmoscatone B1 from 3,4,6-tri-O-acetyl-d-glucal
Author/Authors :
Sabitha، نويسنده , , Gowravaram and Reddy، نويسنده , , S. Siva Sankara and Yadav، نويسنده , , J.S.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
The first stereoselective total synthesis of the natural cryptopyranmoscatone B1 has been accomplished from 3,4,6-tri-O-acetyl-d-glucal. In addition to the double cross-metathesis reaction, a tandem nucleophilic addition-diastereoselective reduction of an in situ generated oxocarbenium cation have been used as key steps to assemble the glycoside moiety of the target molecule.
Keywords :
Cryptopyranmoscatone , Styryllactone , 3 , 6-Tri-O-acetyl-d-glucal , cross-metathesis , ?-C-Glycoside , 4
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
