• Title of article

    An SN2′ displacement approach to allenyl acetates

  • Author/Authors

    Asikainen، نويسنده , , Martta and Lewis، نويسنده , , William and Blake، نويسنده , , Alexander J. and Woodward، نويسنده , , Simon، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2010
  • Pages
    3
  • From page
    6454
  • To page
    6456
  • Abstract
    Reaction of cuprates derived from R3MgBr/CuI/LiBr (R3 = n-alkyl) with R1CCCH(O2CR2)2 (R1 = sp2 hybridised substituent, R2 = mainly Me, alkyl, Ph) provides access to allenyl esters R1R3CCCH(O2CR2) (51–88%). Such species are not accessible via rearrangement of precursor propargylic R1R3C(O2CR2)CCH.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2010
  • Journal title
    Tetrahedron Letters
  • Record number

    1875823