Title of article
On the use of 2-(trimethylsilyl)iodobenzene as a benzyne precursor
Author/Authors
Crossley، نويسنده , , James A. and Kirkham، نويسنده , , James D. and Browne، نويسنده , , Duncan L. and Harrity، نويسنده , , Joseph P.A. Harrity، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
6608
To page
6610
Abstract
A mild method for the generation of benzynes from 2-(trimethylsilyl)iodobenzene derivatives is reported. The employment of silver fluoride in conjunction with caesium fluoride is key for promoting useful levels of elimination and providing benzyne derived products in good yields. Moreover, the substrates are accessed by a novel alkynyl iodide cycloaddition.
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1875937
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