• Title of article

    Catalytic reactions of bis-π-allylpalladium generated from allyltrifluoroborate

  • Author/Authors

    Nakamura، نويسنده , , Hiroyuki and Shimizu، نويسنده , , Kazuki، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2011
  • Pages
    4
  • From page
    426
  • To page
    429
  • Abstract
    Bis-π-allylpalladium-catalyzed nucleophilic allylations to aldehydes 2 and imines 3 have been achieved by replacing allylstannanes with allyltrifluoroborate. Amphiphilic bisallylation of activated olefins 6 with allyltrifluoroborate and allyl acetate also proceeded smoothly in the presence of Pd2(dba)3·CHCl3 and tricyclohexylphosphine catalysts.
  • Keywords
    Allyltrifluoroborate , Bis-?-allylpalladium , allylation , amphiphilic
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2011
  • Journal title
    Tetrahedron Letters
  • Record number

    1876537