Author/Authors :
Park، نويسنده , , Kyungho and Bae، نويسنده , , Goun and Park، نويسنده , , Ahbyeol and Kim، نويسنده , , Yong-Hoe Choe، نويسنده , , Jaehoon and Song، نويسنده , , Kwang Ho and Lee، نويسنده , , Sunwoo، نويسنده ,
Abstract :
Symmetric diarylalkynes were obtained from the decarboxylative coupling reactions of aryl bromides and propiolic acid in water solvent condition. In the presence of phase transfer surfactant C18H37N(CH3)3Cl, the catalytic system of both Pd(PPh3)2Cl2/dppb and Pd(TPPMS)2Cl2/TPPMS afforded the desired coupled products in good yields.
Keywords :
Propiolic acid , PALLADIUM , Decarboxylative coupling , water , microwave