Title of article
The first example of trimethylsilyl methylenenitronate reacting with aldehydes under an apparent Mukaiyama nitro-aldol reaction
Author/Authors
MacDonald، نويسنده , , Frank K. and Carneiro، نويسنده , , Karina M.M. and Pottie، نويسنده , , Ian R.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
891
To page
893
Abstract
Trimethylsilyl methylenenitronate reacts with both aliphatic and aromatic aldehydes in the presence of catalytic amounts of scandium(III) triflate to form the Henry reaction products in low (25%) to good yields (77%). This is the first example of this silyl nitronate undergoing a nitro-aldol reaction under an acid environment.
Keywords
Silyl nitronate , 1 , 2-Nitroalcohol , Henry reaction , Mukaiyama nitro-aldol , Scandium triflate
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1876915
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