Title of article
Arenediazonium salts immobilized in imidazolium ionic liquids as electrophilic partners in the Pd(OAc)2-catalyzed Matsuda–Heck arylation
Author/Authors
R.G. Kalkhambkar، نويسنده , , Rajesh G. and Laali، نويسنده , , Kenneth K.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
5
From page
1733
To page
1737
Abstract
The utility of arenediazonium salts immobilized in imidazolium-ILs [BMIMPF6 and BMIMBF4] for facile, high yielding, synthesis of olefins via the Pd(OAc)2-catalyzed Matsuda–Heck arylation reaction has been demonstrated. The reaction can also be performed as a two-step process in the IL starting from ArNH2, by sequential in-situ diazotization–arylation. Simple product isolation and the recycling/re-use of the IL are additional advantages of this one-pot method.
Keywords
Arenediazonium salts , One-pot diazotization–arylation , Imidazolium ionic liquids , Olefin synthesis , Matsuda–Heck arylation
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877577
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