Title of article
A total synthesis of 11-O-methyldebenzoyltashironin
Author/Authors
Mehta، نويسنده , , Goverdhan and Maity، نويسنده , , Pulakesh، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
1749
To page
1752
Abstract
A concise total synthesis of 11-O-methyldebenzoyltashironin is reported in which oxidative dearomatization-IMDA-RCM triad constitutes the key ring forming steps, while an unorthodox DIBAL-H mediated stereo- and regioselective reductive epoxide openings and implementation of the vinyl bromide–carbonyl equivalency concept were pivotal to the success of this endeavor.
Keywords
natural products , Neurotrophic agents , intramolecular Diels–Alder reaction , Ring closing metathesis , Oxidative dearomatization
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877588
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