Title of article
Solvent-induced hydrogen tunnelling in ascorbate proton-coupled electron transfers
Author/Authors
Karkovi?، نويسنده , , Ana and Brala، نويسنده , , Cvijeta Jakobu?i? and Pilepi?، نويسنده , , Viktor and Ur?i?، نويسنده , , Stanko، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
5
From page
1757
To page
1761
Abstract
The over-the-barrier proton-coupled electron transfer interaction of an ascorbate monoanion with a hexacyanoferrate(III) ion in water entered into a tunnelling regime in water–1,4-dioxane, water–ethanol and water–acetonitrile mixed solvents.
Keywords
Proton-coupled electron transfer , kinetic isotope effect , Hydrogen tunnelling , Dynamics , Ascorbate , solvent
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877592
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