Title of article
Novel synthetic method for allylic amination of cyclic allylic ethers using chlorosulfonyl isocyanate
Author/Authors
Lee، نويسنده , , Sang Hwi and Kim، نويسنده , , In Su and Li، نويسنده , , Qing Ri and Dong، نويسنده , , Guang Ri and Jung، نويسنده , , Young Hoon، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
1901
To page
1904
Abstract
The introduction of amines to allylic or benzylic position of cyclic compounds with chlorosulfonyl isocyanate is developed in high to excellent yields. This method provides a novel access to biologically active compounds including the framework of 1-aminoindanes, 1-aminotetralines, and 1-amino-2-hydroxy cyclic compounds. Mechanistic evidence for the reaction pathway is also provided.
Keywords
1-Aminoindane , 1-Aminotetraline , Allylic carbamate , Chlorosulfonyl isocyanate , Allylic ether , amination
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877691
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