Title of article
Iodoolefinic polypropionate building blocks from vinyl silanes with control of geometry by solvent and by neighboring group participation
Author/Authors
Parker، نويسنده , , Kathlyn A. and Denton، نويسنده , , Richard W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
2
From page
2115
To page
2116
Abstract
Iododesilylation of trisubstituted (Z)-silyl olefins proceeds with retention of geometry in hexafluoroisopropanol (HFIP) but, for unhindered cases, with inversion of geometry in DMSO. When an acyloxy substituent is positioned to participate in the reaction, the protocol consistently leads to inversion of geometry.
Keywords
vinyl iodide , Solvent effect , anchimeric assistance , Iododesilylation , Polypropionate
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877822
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