Title of article
Confirmation of the absolute configuration of (−)-aurantioclavine
Author/Authors
Behenna، نويسنده , , Douglas C. and Krishnan، نويسنده , , Shyam and Stoltz، نويسنده , , Brian M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
2152
To page
2154
Abstract
We confirm our previous assignment of the absolute configuration of (−)-aurantioclavine as 7R by crystallographically characterizing an advanced 3-bromoindole intermediate reported in our previous synthesis. This analysis also provides additional support for our model of enantioinduction in the palladium(II)-catalyzed oxidative kinetic resolution of secondary alcohols.
Keywords
Aurantioclavine , Oxidative kinetic resolution , absolute configuration , indole alkaloid , Azepinoindole
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877849
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