Title of article
Self-assembly of coordinative supramolecular polygons with open binding sites
Author/Authors
Zheng، نويسنده , , Yao-Rong and Wang، نويسنده , , Ming and Kobayashi، نويسنده , , Shiho and Stang، نويسنده , , Peter J.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
2188
To page
2191
Abstract
The design and synthesis of coordinative supramolecular polygons with open binding sites is described. Coordination-driven self-assembly of 2,6-bis(pyridin-4-ylethynyl)pyridine with 60° and 120° organoplatinum acceptors results in quantitative formation of a supramolecular rhomboid and hexagon, respectively, both bearing open pyridyl binding sites. The structures were determined by multinuclear (31P and 1H) NMR spectroscopy and electrospray ionization (ESI) mass spectrometry, along with a computational study.
Keywords
Coordination-driven self-assembly , Open binding sites , Supramolecular polygons
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877873
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