Title of article
Efficient two directional syntheses of a homophthalate ester and novel resorcylate oligomers
Author/Authors
Patel، نويسنده , , Bhavesh H. and Heath، نويسنده , , Scott F.A. and Mason، نويسنده , , Andrew M. and Barrett، نويسنده , , Anthony G.M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
2258
To page
2261
Abstract
Thermolysis of 6,6′-(2-oxopropane-1,3-diyl)bis(2,2-dimethyl-4H-1,3-dioxin-4-one) in the presence of methanol gave a triketo-ester which subsequently aromatized to provide a synthetically useful homophthalate ester. Enolate C-acylation in the presence of diethylzinc was used to synthesize other double diketo-dioxinones, which on cyclization, aromatization and dioxinone ring opening gave novel double resorcylate derivatives.
Keywords
Resorcylate , Double dioxinone , Homophthalate ester , aromatization
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877925
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