Author/Authors :
Wang، نويسنده , , Cheng and Gan، نويسنده , , Zubao and Lu، نويسنده , , Ji and Wu، نويسنده , , Xia and Song، نويسنده , , Zhenlei، نويسنده ,
Abstract :
A highly stereoselective approach to tetrasubstituted (E)-β-hydroxy silyl enol ethers is described. The reaction proceeds via a sequential addition/[1,2]-Brook rearrangement/epoxide-opening process of aryl-substituted oxiranyl anions with acylsilanes.
Keywords :
Acylsilane , Oxiranyl anion , Brook rearrangement , Silyl enol ether
