Title of article
A synthesis of 2-epi-fagomine using gold(I)-catalysed allene cyclisation
Author/Authors
Bates، نويسنده , , Roderick W. and Shuyi Ng، نويسنده , , Pearly، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
2969
To page
2971
Abstract
A synthesis of 2-epi-fagomine via a highly stereoselective gold(I)-catalysed allene cyclisation is described. The stereochemical outcome of the cyclisation is opposite to that observed in previous studies. In contrast, gold(III)-catalysed cyclisation is inefficient and gives rise to double cyclisation by-products.
Keywords
Gold , Piperidine , Aza-sugar , Allene
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878434
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