Title of article :
A chromium-free synthesis of enantiopure 5-oxoborneol
Author/Authors :
Pierluigi and Tartaggia، نويسنده , , Stefano and Padovan، نويسنده , , Pierluigi and Borsato، نويسنده , , Giuseppe and De Lucchi، نويسنده , , Ottorino and Fabris، نويسنده , , Fabrizio، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
Enantiopure (−)-5-oxoborneol was obtained in 35% overall yield in two steps, starting from readily available (−)-bornyl acetate and using oxone® as a safe and inexpensive oxidant. The reported procedure avoids the use of large excess of noxious chromium(VI), which was required by the so far reported syntheses.
Keywords :
Oxone® , Ruthenium , terpene , Borneol , Camphor , Catalysis , Oxidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
