Author/Authors :
Gomes، نويسنده , , Ana T.P.C. and Almeida Paz، نويسنده , , Filipe A. and Neves، نويسنده , , Maria G.P.M.S. and Tomé، نويسنده , , Augusto C. and Silva، نويسنده , , Artur M.S. and de Souza، نويسنده , , Maria Cecيlia B.V. and Ferreira، نويسنده , , Vيtor F. and Cavaleiro، نويسنده , , José A.S.، نويسنده ,
Abstract :
The catalytic insertion of ethyl diazoacetate into a porphyrin derivative bearing an NH2 substituent, in the presence of a Rh-based catalyst, was investigated. The X-ray analysis of one of the isolated products reveals the formation of a chiral supramolecular system.
Keywords :
Porphyrin , insertion reaction , Carbene , Ethyl diazoacetate
