Title of article :
Oxidative rearrangement of 2-furylcarbamates with dimethyldioxirane: a high-yielding preparation of 5-hydroxypyrrol-2(5H)-ones
Author/Authors :
Boukouvalas، نويسنده , , John and Loach، نويسنده , , Richard P. and Ouellet، نويسنده , , Etienne، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
A mild, general and efficient method for the oxidative rearrangement of 2-furylcarbamates to N-Boc-5-hydroxypyrrol-2(5H)-ones is reported. The feasibility of removing the Boc group from the products was demonstrated by the synthesis of two hitherto unknown 5-aryl-5-hydroxypyrrol-2(5H)-ones.
Keywords :
Oxidation , Shioiri–Yamada reagent , Curtius rearrangement , Lactam , Magnesium perchlorate
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
