Title of article
Oxidative rearrangement of 2-furylcarbamates with dimethyldioxirane: a high-yielding preparation of 5-hydroxypyrrol-2(5H)-ones
Author/Authors
Boukouvalas، نويسنده , , John and Loach، نويسنده , , Richard P. and Ouellet، نويسنده , , Etienne، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
5047
To page
5050
Abstract
A mild, general and efficient method for the oxidative rearrangement of 2-furylcarbamates to N-Boc-5-hydroxypyrrol-2(5H)-ones is reported. The feasibility of removing the Boc group from the products was demonstrated by the synthesis of two hitherto unknown 5-aryl-5-hydroxypyrrol-2(5H)-ones.
Keywords
Oxidation , Shioiri–Yamada reagent , Curtius rearrangement , Lactam , Magnesium perchlorate
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879286
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