Author/Authors :
Oda، نويسنده , , Yoshiro and Hirano، نويسنده , , Koji and Satoh، نويسنده , , Tetsuya and Kuwabata، نويسنده , , Susumu and Miura، نويسنده , , Masahiro، نويسنده ,
Abstract :
The transition-metal-free aerobic oxidation of benzylic alcohols is uniquely accelerated by a 1-butyl-3-methylimidazolium hexafluorophosphate (BMI-PF6)/PhCF3 biphasic system and Cs2CO3 to afford the corresponding ketones in good yields. The reaction system is also applicable to an oxidative cross-esterification of primary benzyl alcohols with a higher aliphatic alcohol.
Keywords :
Ketone , Aerobic oxidation , alcohol , Ester , Ionic liquid
