• Title of article

    A remarkable effect of ionic liquids in transition-metal-free aerobic oxidation of benzylic alcohols

  • Author/Authors

    Oda، نويسنده , , Yoshiro and Hirano، نويسنده , , Koji and Satoh، نويسنده , , Tetsuya and Kuwabata، نويسنده , , Susumu and Miura، نويسنده , , Masahiro، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2011
  • Pages
    3
  • From page
    5392
  • To page
    5394
  • Abstract
    The transition-metal-free aerobic oxidation of benzylic alcohols is uniquely accelerated by a 1-butyl-3-methylimidazolium hexafluorophosphate (BMI-PF6)/PhCF3 biphasic system and Cs2CO3 to afford the corresponding ketones in good yields. The reaction system is also applicable to an oxidative cross-esterification of primary benzyl alcohols with a higher aliphatic alcohol.
  • Keywords
    Ketone , Aerobic oxidation , alcohol , Ester , Ionic liquid
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2011
  • Journal title
    Tetrahedron Letters
  • Record number

    1879372