Title of article
A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis
Author/Authors
Chung، نويسنده , , William and Lindovska، نويسنده , , Petra and Camp، نويسنده , , Jason E.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
6785
To page
6787
Abstract
A step-economical one-pot nucleophilic catalysis/thermal Claisen-rearrangement protocol for the direct synthesis of α-formyl-α-allylacetates from allylic alcohols and activated alkynes has been developed. The product α-formyl-α-allylacetates were further reacted in situ to give either protected enol ethers or β-hydroxy-4-pentenoates.
Keywords
Dabco , Claisen-rearrangement , Step-economical , nucleophilic catalysis , One-pot
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879711
Link To Document