Title of article
A facile preparation of tetralins from arene-1,4-diones using titanium(IV) chloride and triethylsilane
Author/Authors
Li، نويسنده , , Gang and Xiao، نويسنده , , Qiong and Li، نويسنده , , Chun and Wang، نويسنده , , Xiaojian and Yin، نويسنده , , Dali، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
6827
To page
6830
Abstract
A facile method for the synthesis of tetralins has been described which uses various substituted phenylpentane-1,4-diones as starting material with a combination of TiCl4/Et3SiH. The synthesis involves three reactions under mild conditions. A mechanism has been proposed for the reductive cyclization through ionic hydrogenation, and titanium(IV) chloride catalyzed cyclization.
Keywords
Tetralin , 4-dione , Intramolecular cyclization , Ionic hydrogenation , Arene-1
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879721
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