Title of article :
Direct oxidative phosphonylation of amines under metal-free conditions
Author/Authors :
Wang، نويسنده , , Haolong and Li، نويسنده , , Xincheng and Wu، نويسنده , , Fan and Wan، نويسنده , , Boshun، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Direct oxidation coupling of tertiary amines and dialkyl- or diphenyl-substituted phosphonates was developed. The reaction was mediated by DDQ under room temperature. Various phosphonates and N-aryl tetrahydroisoquinolines were tolerated in this reaction, and α-aminophosphonates were obtained with up to 99% yield.
Keywords :
DDQ , Tertiary amine , Phosphonation , oxidative coupling
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
